Angelina Jolie, 41, and Brad Pitt, 52, met on the set of Mr and Mrs Smith in 2004.
Jolie and Pitt were rumored to be an item after the success of their movie together, yet, neither confirmed their relationship until 2005.
Both Jolie and Pitt were partners for nine years before officially becoming married in 2014.
Unarguably one of Hollywood’s most high profile couple, Brangelina split, Tuesday, after being officially married for two years.
Angelina cited “irreconcilable differences” just as Brad Pitt said he felt “saddened” at divorcing Jolie.
The World War Z actor added that what mattered was the welfare of their kids. He also requested privacy from the press.
Read: #BrangelinaOver: Angelina Jolie Files For Divorce From Brad Pitt
The couple have six children together: Vivienne, 7; Knox, 7; Shiloh, 9; Zahara, 11; Pax, 12; and Maddox 14.
A look at some of Angelina Jolie and Brad Pitt’s best moments